Electrochemical Energy Reviews ›› 2019, Vol. 2 ›› Issue (2): 332-371.doi: 10.1007/s41918-019-00033-7

所属专题: Fundamental Electrochemistry

• REVIEW ARTICLE • 上一篇    

3D Hierarchical Porous Graphene-Based Energy Materials: Synthesis, Functionalization, and Application in Energy Storage and Conversion

Cheng Tang1,2, Hao-Fan Wang1,3, Jia-Qi Huang4, Weizhong Qian1, Fei Wei1, Shi-Zhang Qiao2, Qiang Zhang1   

  1. 1 Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
    2 School of Chemical Engineering, The University of Adelaide, Adelaide, SA 5005, Australia;
    3 AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory(ChEM-OIL), National Institute of Advanced Industrial Science and Technology(AIST), Yoshida, Sakyo-ku, Kyoto 606-8501, Japan;
    4 Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
  • 收稿日期:2019-01-02 修回日期:2019-01-24 出版日期:2019-06-20 发布日期:2019-06-28
  • 通讯作者: Qiang Zhang E-mail:zhang-qiang@mails.tsinghua.edu.cn
  • 基金资助:
    This work is supported by the National Key Research and Development Program (2016YFA0202500 and 2016YFA0200102) and the National Natural Science Foundation of China (21676160, 21825501, and U1801257).

3D Hierarchical Porous Graphene-Based Energy Materials: Synthesis, Functionalization, and Application in Energy Storage and Conversion

Cheng Tang1,2, Hao-Fan Wang1,3, Jia-Qi Huang4, Weizhong Qian1, Fei Wei1, Shi-Zhang Qiao2, Qiang Zhang1   

  1. 1 Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
    2 School of Chemical Engineering, The University of Adelaide, Adelaide, SA 5005, Australia;
    3 AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory(ChEM-OIL), National Institute of Advanced Industrial Science and Technology(AIST), Yoshida, Sakyo-ku, Kyoto 606-8501, Japan;
    4 Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
  • Received:2019-01-02 Revised:2019-01-24 Online:2019-06-20 Published:2019-06-28
  • Contact: Qiang Zhang E-mail:zhang-qiang@mails.tsinghua.edu.cn
  • Supported by:
    This work is supported by the National Key Research and Development Program (2016YFA0202500 and 2016YFA0200102) and the National Natural Science Foundation of China (21676160, 21825501, and U1801257).

摘要: The rational development of efective energy materials is crucial to the sustainable growth of society. Here, 3D hierarchical porous graphene (hpG)-based materials with micro-, meso-, and macroporous features have recently attracted extensive research eforts due to unique porosities, controllable synthesis, versatile functionalization, favorable mass/electron transport, and superior performances in which corresponding electrochemical performances are strongly dependent on the nature of the building blocks and structural hierarchy of the assemblies. In this review, recent achievements in the controllable synthesis, versatile functionalization, and device application of 3D hpG-based energy materials will be summarized, including controllable and facile synthesis through chemical vapor deposition on 3D porous templates, post-assembly/treatment of graphene oxide nanosheets, and templated polymerization. In addition, graphene material functionalization through heteroatom doping, spatially confned decoration of active nanoparticles, and surface hybridization of graphene-analogous components to enhance electrochemical properties will be discussed. Furthermore, applications of 3D hpG materials in various electrochemical energy storage and conversion systems will be summarized, including lithium-ion batteries, lithium-sulfur batteries, lithium metal anodes, oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, and nitrogen reduction reaction. Overall, this review will comprehensively present the property advantages, design principles and synthesis strategies of 3D hpG-based energy materials and provide guidance in the development of various 2D graphene-analogous materials and nanomaterials for advanced electrochemical energy storage and conversion systems.

Full-text:https://link.springer.com/article/10.1007/s41918-019-00033-7/fulltext.html

关键词: Graphene, Nanostructures, Hybrid, Li ion battery, Li sulfur batteries, Oxygen reduction reaction, Oxygen evolution reaction, Nitrogen reduction reaction

Abstract: The rational development of efective energy materials is crucial to the sustainable growth of society. Here, 3D hierarchical porous graphene (hpG)-based materials with micro-, meso-, and macroporous features have recently attracted extensive research eforts due to unique porosities, controllable synthesis, versatile functionalization, favorable mass/electron transport, and superior performances in which corresponding electrochemical performances are strongly dependent on the nature of the building blocks and structural hierarchy of the assemblies. In this review, recent achievements in the controllable synthesis, versatile functionalization, and device application of 3D hpG-based energy materials will be summarized, including controllable and facile synthesis through chemical vapor deposition on 3D porous templates, post-assembly/treatment of graphene oxide nanosheets, and templated polymerization. In addition, graphene material functionalization through heteroatom doping, spatially confned decoration of active nanoparticles, and surface hybridization of graphene-analogous components to enhance electrochemical properties will be discussed. Furthermore, applications of 3D hpG materials in various electrochemical energy storage and conversion systems will be summarized, including lithium-ion batteries, lithium-sulfur batteries, lithium metal anodes, oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, and nitrogen reduction reaction. Overall, this review will comprehensively present the property advantages, design principles and synthesis strategies of 3D hpG-based energy materials and provide guidance in the development of various 2D graphene-analogous materials and nanomaterials for advanced electrochemical energy storage and conversion systems.

Full-text:https://link.springer.com/article/10.1007/s41918-019-00033-7/fulltext.html

Key words: Graphene, Nanostructures, Hybrid, Li ion battery, Li sulfur batteries, Oxygen reduction reaction, Oxygen evolution reaction, Nitrogen reduction reaction