Electrochemical Energy Reviews ›› 2019, Vol. 2 ›› Issue (2): 312-331.doi: 10.1007/s41918-019-00034-6

所属专题: Hydrogen Generation and Storage

• REVIEW ARTICLE • 上一篇    下一篇

The Hydrogen Oxidation Reaction in Alkaline Medium: An Overview

Carlos Augusto Campos-Roldán1,2, Nicolas Alonso-Vante1   

  1. 1 IC2 MP, UMR-CNRS 7285, University of Poitiers, 4 rue Michel Brunet, 86022 Poitiers, France;
    2 Instituto Politécnico Nacional-ESIQIE, Laboratorio de Electroquímica y Corrosión, UPALM, 07738 CDMX, Mexico
  • 收稿日期:2018-12-20 修回日期:2019-02-07 出版日期:2019-06-20 发布日期:2019-06-28
  • 通讯作者: Nicolas Alonso-Vante E-mail:nicolas.alonso.vante@univ-poitiers.fr
  • 基金资助:
    CA.C.R. acknowledges CONACyT-Mexico Scholarship Nr. MX-561206. The authors acknowledge financial support from the European Union (ERDF) and "Région Nouvelle Aquitaine".

The Hydrogen Oxidation Reaction in Alkaline Medium: An Overview

Carlos Augusto Campos-Roldán1,2, Nicolas Alonso-Vante1   

  1. 1 IC2 MP, UMR-CNRS 7285, University of Poitiers, 4 rue Michel Brunet, 86022 Poitiers, France;
    2 Instituto Politécnico Nacional-ESIQIE, Laboratorio de Electroquímica y Corrosión, UPALM, 07738 CDMX, Mexico
  • Received:2018-12-20 Revised:2019-02-07 Online:2019-06-20 Published:2019-06-28
  • Contact: Nicolas Alonso-Vante E-mail:nicolas.alonso.vante@univ-poitiers.fr
  • Supported by:
    CA.C.R. acknowledges CONACyT-Mexico Scholarship Nr. MX-561206. The authors acknowledge financial support from the European Union (ERDF) and "Région Nouvelle Aquitaine".

摘要: The recent advances in electrocatalysis for the hydrogen evolution reactions in acid and alkaline media are carefully reviewed. In this sense, this short review focuses on precious and non-precious catalytic centers. The recent development of HOR electrocatalysts with novel structures and compositions is highlighted. The understandings of the correlation between the activity and the shape, size, composition, and synthesis methods are summarized. The research directions, e.g., on the further development of more active, more stable, and less expensive electrocatalysts for the anion-exchange membranes for the alkaline fuel cell technology are provided. In this context, positive perspectives to overcome the high kinetic barriers encountered in alkaline medium can be expected in the years to come.

Full-text:https://link.springer.com/article/10.1007/s41918-019-00034-6/fulltext.html

关键词: Hydrogen oxidation reaction, Alkaline medium, Precious metals, Non-precious metals

Abstract: The recent advances in electrocatalysis for the hydrogen evolution reactions in acid and alkaline media are carefully reviewed. In this sense, this short review focuses on precious and non-precious catalytic centers. The recent development of HOR electrocatalysts with novel structures and compositions is highlighted. The understandings of the correlation between the activity and the shape, size, composition, and synthesis methods are summarized. The research directions, e.g., on the further development of more active, more stable, and less expensive electrocatalysts for the anion-exchange membranes for the alkaline fuel cell technology are provided. In this context, positive perspectives to overcome the high kinetic barriers encountered in alkaline medium can be expected in the years to come.

Full-text:https://link.springer.com/article/10.1007/s41918-019-00034-6/fulltext.html

Key words: Hydrogen oxidation reaction, Alkaline medium, Precious metals, Non-precious metals